1446558-39-9

Upstream product

• 105786-34-3 ethyl endo-3-aminobicyclo<2.2.1>hept-5-ene-2-endo-carboxylate 
• 98-88-4 benzoyl chloride 
• 1446558-37-7 ethyl (1S,2R,3R,5S)-2-benzoylamino-3,5-divinylcyclopentanecarboxylate 
• 1446558-36-6 ethyl (1S,2R,3S,5R)-2-benzamido-3,5-diformylcyclopentanecarboxylate 
• 1446558-34-4 ethyl (1S,2S,3R,4R)-3-benzamidobicyclo[2.2.1]hept-5-ene-2-carboxylate 
• 1446558-33-3 C₁₀H₁₅NO₂*ClH 
• 924272-78-6 (1R,2R,5S,6S)-3-azatricyclo[4.2.1.0^2,5]non-7-en-4-one 
• 14735-70-7 diexo-3-Aza-4-oxotricyclo<4.2.1.0^2,5>non-7-ene 

Relevant academic research and scientific papers

Synthesis of novel functionalized cispentacins through C-C oxidative cleavage of diendo-norbornene β-amino acid

Difunctionalized cispentacin derivatives with two new stereogenic centres have been synthesized from a diendo-norbornene β-amino acid in a stereocontrolled route, involving C-C double bond functionalization by dihydroxylation, followed by oxidative ring cleavage and transformation of the dialdehyde intermediates through a Wittig reaction.

A new access route to functionalized cispentacins from norbornene β-amino acids

An efficient and simple new stereocontrolled access route to novel disubstituted cispentacin derivatives with multiple stereogenic centers from norbornene β-lactam has been developed. The synthesis involves olefinic bond functionalization by dihydroxylation followed by oxidative ring cleavage and transformation of the dialdehyde intermediate through a Wittig reaction. Copyright