1446710-78-6Relevant articles and documents
Novel spiroketal-based diphosphite ligands for hydroformylation of terminal and internal olefins
Jia, Xiaofei,Wang, Zheng,Xia, Chungu,Ding, Kuiling
, p. 1901 - 1904 (2013)
Spiroketal-based diphosphite ligands have been developed for the rhodium-catalyzed hydroformylation reaction. Under the optimized reaction conditions, a turnover number (TON) of up to 2.4 × 104 and a linear to branched ratio (l/b) of up to 93 were obtained in the hydroformylation of terminal olefins. The catalysts were also found to be effective in the isomerization-hydroformylation of some internal olefins.