144675-70-7Relevant academic research and scientific papers
Synthesis of Cyclopentylamines using Zirconium Chemistry
Davis, Jeremy M.,Whitby, Richard J.,Jaxa-Chamiec, Albert
, p. 1445 - 1448 (1994)
Insertion of alkyl or trialkylsilyl isocyanides into zirconacyclopentanes gives iminoacyl complexes which rearrange to zirconocene η2-imine complexes on heating.These may insert alkynes to give 1-vinyl-1-cyclopentylamines on work up, or decomplex the zirconium to afford, after hydrolysis, cyclopentanones.With benzyl isocyanide 1,2-migration of the η2-imine complexes occurs before quenching.
