Tetrahedron Letters p. 1445 - 1448 (1994)
Update date:2022-08-02
Topics:
Davis, Jeremy M.
Whitby, Richard J.
Jaxa-Chamiec, Albert
Insertion of alkyl or trialkylsilyl isocyanides into zirconacyclopentanes gives iminoacyl complexes which rearrange to zirconocene η2-imine complexes on heating.These may insert alkynes to give 1-vinyl-1-cyclopentylamines on work up, or decomplex the zirconium to afford, after hydrolysis, cyclopentanones.With benzyl isocyanide 1,2-migration of the η2-imine complexes occurs before quenching.
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