Tetrahedron Letters p. 1445 - 1448 (1994)
Update date:2022-08-02
Topics:
Davis, Jeremy M.
Whitby, Richard J.
Jaxa-Chamiec, Albert
Insertion of alkyl or trialkylsilyl isocyanides into zirconacyclopentanes gives iminoacyl complexes which rearrange to zirconocene η2-imine complexes on heating.These may insert alkynes to give 1-vinyl-1-cyclopentylamines on work up, or decomplex the zirconium to afford, after hydrolysis, cyclopentanones.With benzyl isocyanide 1,2-migration of the η2-imine complexes occurs before quenching.
View MoreShanghai Dano Pharmaceutical Co.,Ld.(expird)
Contact:+86-592-6266840
Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
Contact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Chongqing Shuangfeng Chemical Co.,Ltd
Contact:+86-23-49850156
Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Anqing World Chemical Co., Ltd.
Contact:+86-556-5800026
Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Zhejiang Sanmei Chemical Industry Co., Ltd
Contact:86-579-87633213
Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Doi:10.1002/anie.201100417
(2011)Doi:10.1002/anie.201408457
(2014)Doi:10.1021/om200377e
(2011)Doi:10.1002/hlca.194402701107
(1944)Doi:10.1021/ja204474v
(2011)Doi:10.1021/op500026z
(2014)
