144675-79-6Relevant articles and documents
Formation of zirconocene η2-imine complexes by rearrangement of cyclic iminoacyl complexes
Davis,Whitby,Jaxa-Chamiec
, p. 5655 - 5658 (2007/10/02)
Insertion of phenylisocyanide into bicyclic zirconacyclopentanes, obtained from a 1,7-octa- or 1,6-hepta-diene by reaction with dibutylzirconocene, affords initially an iminoacyl complex that rearranges on warming to form a zirconocene η2-imine complex which inserts unactivated alkenes and alkynes.