3710-30-3 Usage
Chemical Properties
CLEAR COLORLESS TO SLIGHTLY YELLOW LIQUID
Uses
Different sources of media describe the Uses of 3710-30-3 differently. You can refer to the following data:
1. 1,7-Octadiene is used in organic synthesis. It is also used to study and assess the structure and reaction rate in olefin ring-closing metathesis of a series of simple dienes. Further, it is used in a study to investigate micropatterned surfaces prepared by plasma polymerization. It acts as a crosslinker as well as a source of ethylene in cross-enyne metathesis (CEYM)-related reactions.
2. 1,7-Octadiene has been used in a study to assess the structure and reaction rate in olefin ring-closing metathesis of a series of simple dienes. It has also been used in a study to investigate micropatterned surfaces prepared by plasma polymerization.
General Description
1,7-Octadiene can serve as a crosslinker and source of ethylene for a variant of Mori′s conditions in CEYM-related reactions.
Flammability and Explosibility
Highlyflammable
Safety Profile
Mildly toxic by ingestion,inhalation and skin contact. A very dangerous fire hazardwhen exposed to heat or flame; can react vigorously withoxidizing materials. When heated to decomposition itemits acrid smoke and irritating fumes.
Check Digit Verification of cas no
The CAS Registry Mumber 3710-30-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,7,1 and 0 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 3710-30:
(6*3)+(5*7)+(4*1)+(3*0)+(2*3)+(1*0)=63
63 % 10 = 3
So 3710-30-3 is a valid CAS Registry Number.
InChI:InChI=1/C8H14/c1-3-5-7-8-6-4-2/h3-4H,1-2,5-8H2
3710-30-3Relevant articles and documents
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Gardner,Wright
, p. 163 (1972)
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Tsuji,J.,Yamakawa,T.
, p. 613 - 616 (1979)
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Takamuku et al.
, p. 2562 (1971)
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Photoredox-Assisted Reductive Cross-Coupling: Mechanistic Insight into Catalytic Aryl-Alkyl Cross-Couplings
Paul, Avishek,Smith, Mark D.,Vannucci, Aaron K.
, p. 1996 - 2003 (2017/02/26)
Here, we describe a photoredox-assisted catalytic system for the direct reductive coupling of two carbon electrophiles. Recent advances have shown that nickel catalysts are active toward the coupling of sp3-carbon electrophiles and that well-controlled, light-driven coupling systems are possible. Our system, composed of a nickel catalyst, an iridium photosensitizer, and an amine electron donor, is capable of coupling halocarbons with high yields. Spectroscopic studies support a mechanism where under visible light irradiation the Ir photosensitizer in conjunction with triethanolamine are capable of reducing a nickel catalyst and activating the catalyst toward cross-coupling of carbon electrophiles. The synthetic methodology developed here operates at low 1 mol % catalyst and photosensitizer loadings. The catalytic system also operates without reaction additives such as inorganic salts or bases. A general and effective sp2-sp3 cross-coupling scheme has been achieved that exhibits tolerance to a wide array of functional groups.
