1446944-75-7

Upstream product

• 7540-51-4 (S)-3,7-dimethyl-6-octen-1-ol 
• 67245-14-1 (3S,6RS)-1-benzyloxy-6,7-epoxy-3,7-dimethyloctane 
• 1446944-33-7 (S)-6-benzyloxy-4-methylhexyl iodide 
• 79015-77-3 (R)-(+)-5,9-dimethyldec-8-en-1-yne 
• 5949-05-3 (S)-Citronellal 
• 173913-23-0 (R)-5,9-dimethyl-1-(trimethylsilyl)-dec-8-en-1-yne 
• 55816-07-4 (R)-3,7-dimethyl-6-octenyl iodide 
• 67214-54-4 (R)-citronellyl tosylate 
• 1117-61-9 (3R)-citronellol 

Downstream Products

• 1446944-84-8 (3S,11R)-1-benzyloxy-3,11-dimethyl-14-pentadecen-7-yne 
• 1446944-81-5 (4S,12S)-14-benzyloxy-4,12-dimethyl-7-tetradecynal 
• 1446944-78-0 (3S,11S,14RS)-1-benzyloxy-14,15-epoxy-3,11,15-trimethyl-7-hexadecyne 
• 1446944-90-6 (3S,11R)-3,11-dimethylpentadecyl tosylate 

Relevant academic research and scientific papers

Synthesis of all the stereoisomers of 6-methyl-2-octadecanone, 14-methyl-2-octadecanone, and 6,14-dimethyl-2-octadecanone, sex pheromone components of the Lyclene dharma dharma moth, from the enantiomers of citronellal

The enantiomers of citronellal were converted to all the stereoisomers of 6-methyl-2-octadecanone, 14-methyl-2-octadecanone, and 6,14-dimethyl-2- octadecanone, the female-produced sex pheromone components of the Lyclene dharma dharma moth. Three wellestablished procedures, the Wittig reaction, alkylation of alkynes, and acetoacetic ester synthesis, were employed for the carbon-carbon bond formation to connect the building blocks.