144704-72-3Relevant academic research and scientific papers
Total Synthesis of Mugineic Acid. Efficient Use of the Phenyl Group as the Carboxyl Synthon
Matsuura, Fumiyoshi,Hamada, Yasumasa,Shioiri, Takayuki
, p. 8211 - 8222 (1993)
Stereoselective total synthesis of mugineic acid (1), a unique phytosiderophore from roots of barley, has been achieved from readily available (2S,3S)- and (2R,3R)-2,3-epoxycinnamyl alcohols (5) and (6).The key step is the oxidation of the phenyl group to the carboxylic acid by use of the ruthenium trichloride-sodium metaperiodate system.
A Synthesis of A γ-Azetidinyl-β-hydroxy-α-amino Acid Derivative, A Key Intermediate for the Synthesis of Mugineic Acid
Matsuura, Fumiyoshi,Hamada, Yasumasa,Shioiri, Takayuki
, p. 1069 - 1074 (2007/10/02)
The γ-azetidinyl-β-hydroxy-α-amino acid derivative 2, a key intermediate for the total synthesis of mugineic acid (1), was stereoselectively prepared from readily available (2R,3R)-epoxysuccinic acid (3).
