144707-42-6Relevant articles and documents
A Rh(II)-catalyzed cycloaddition approach toward the synthesis of komaroviquinone
Padwa, Albert,Chughtai, Majid J.,Boonsombat, Jutatip,Rashatasakhon, Paitoon
, p. 4758 - 4767 (2008/09/20)
Using a rhodium(II)-catalyzed cyclization/cycloaddition sequence as the key reaction step, the icetexane core of komaroviquinone was constructed by an intramolecular dipolar-cycloaddition of a carbonyl ylide dipole across a tethered π-bond. The ylide was arrived at by cyclization of a rhodium carbenoid intermediate onto a proximal ester group. Efforts toward the preparation of the required precursor for elaboration to the natural product are discussed.
Approach to the synthesis of candelabrone and synthesis of 3,7-diketo-12-hydroxyabieta-8,11,13-triene
Burnell, Robert H.,Caron, Stephane
, p. 1446 - 1454 (2007/10/02)
An approach to the synthesis of aromatic diterpenes was tested for its generality.Phenylacetonitriles with increasing substitution on the aromatic ring were prepared and alkylated with geranyl bromide and the resulting dienes subjected to cationic cycliza
