1447728-94-0Relevant articles and documents
Preparation and palladium-mediated cross-coupling of α- benzoyloxyalkylzinc bromides
Sakata, Komei,Urabe, Daisuke,Inoue, Masayuki
, p. 4189 - 4192 (2013/07/26)
Here we report a two-step preparation protocol of α- benzoyloxyalkylzinc bromides from α-benzoyloxyalkyl selenides, and their application to palladium-catalyzed cross-coupling reactions with aryl and vinyl iodides. The developed method effectively provides a variety of benzoyl-protected benzylic and allylic alcohol derivatives through the formation of C(sp3)-C(sp2) bonds without affecting various polar functional groups.