144775-07-5

Upstream product

• 144581-86-2 α-Bromo-N-p-methoxybenzylacetamide 
• 2393-23-9 4-methoxy-benzylamine 
• 117471-50-8 N,N'-bis(p-methoxybenzyl)-α-aminoacetamide 
• 144581-87-3 2-Bromo-N-(4-methoxy-benzyl)-N-[(4-methoxy-benzylcarbamoyl)-methyl]-acetamide 
• 603-35-0 triphenylphosphine 

Downstream Products

• 144581-89-5 5-Benzyloxy-3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-pentanoic acid (4-methoxy-benzyl)-[(4-methoxy-benzylcarbamoyl)-methyl]-amide 
• 144581-92-0 3-(3-Benzyloxy-propionyl)-3-(tert-butyl-dimethyl-silanyloxy)-1,4-bis-(4-methoxy-benzyl)-piperazine-2,5-dione 
• 144581-93-1 (R)-3-((S)-3-Benzyloxy-1-hydroxy-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-1,4-bis-(4-methoxy-benzyl)-piperazine-2,5-dione 
• 144581-91-9 3-(3-Benzyloxy-propionyl)-3-hydroxy-1,4-bis-(4-methoxy-benzyl)-piperazine-2,5-dione 
• 105199-00-6 3-(3-benzyloxy-1-hydroxypropyl)-3-hydroxy-1,4-bis(p-methoxybenzyl)-2,5-piperazinedione 
• 144581-90-8 5-Benzyloxy-2,3-dioxo-pentanoic acid (4-methoxy-benzyl)-[(4-methoxy-benzylcarbamoyl)-methyl]-amide 
• 144581-88-4 N-(4-Methoxy-benzyl)-N-[(4-methoxy-benzylcarbamoyl)-methyl]-2-(triphenyl-λ⁵-phosphanylidene)-acetamide 

Relevant academic research and scientific papers

Oxidation of α-ylido, β-keto amides to vicinal tricarbonyls. Synthesis of a diketopiperazine precursor of bicyclomycin

The Yoshimura intermediate in the total synthesis of bicyclomycin was prepared by intramolecular addition of an amide to an α,β-diketoamide. The resulting unsymmetrical diketopiperazine was then converted to the diol-ether target.