117471-50-8

Upstream product

• 2393-23-9 4-methoxy-benzylamine 
• 144581-86-2 α-Bromo-N-p-methoxybenzylacetamide 

Downstream Products

• 117471-51-9 N-(p-methoxybenzyl)-2-acetamide 
• 135366-03-9 6,8-bis(p-methoxybenzyl)-6,8-diaza-<(tert-butyldimethylsilyl)oxy>-3-<(phenylselenyl)methyl>bicyclo<2.2.2>octane-5,7-dione 
• 135365-96-7 (Z)-9,11-bis(p-methoxybenzyl)-9,11-diaza-7-<(tert-butyldimethylsilyl)oxy>-2-oxabicyclo<5.2.2>undec-4-ene-8,10-dione 
• 135366-00-6 6,8-bis(p-methoxybenzyl)-6,8-diaza-4-<(tert-butyldimethylsilyl)oxy>-2-ethenyl-1-hydroxybicyclo<2.2.2>octane-5,7-dione 
• 135366-01-7 6,8-bis(p-methoxybenzyl)-6,8-diaza-4-<(tert-butyldimethylsilyl)oxy>-2-ethenyl-1-hydroxybicyclo<3.2.1>octane-5,7-dione 
• 135366-02-8 6,8-bis(p-methoxybenzyl)-6,8-diaza-4-<(tert-butyldimethylsilyl)oxy>-3-(hydroxymethyl)bicyclo<2.2.2>octane-5,7-dione 
• 135393-45-2 6,8-bis(p-methoxybenzyl)-6,8-diaza-1-dihydroxy-2-ethenylbicyclo<2.2.2>octane-5,7-dione 
• 135365-95-6 (Z)-9,11-bis(p-methoxybenzyl)-9,11-diaza-7-hydroxy-2-oxabicyclo<5.2.2>undec-4-ene-8,10-dione 
• 135365-98-9 6,8-bis(p-methoxybenzyl)-6,8-diaza-1-hydroxy-4-methyl-2-ethenyl-bicyclo<2.2.2>octane-5,7-dione 
• 135365-94-5 (Z)-9,11-bis(p-methoxybenzyl)-9,11-diaza-7-methyl-2-oxabicyclo<5.2.2>undec-4-ene-8,10-dione 
• 135365-97-8 6,8-bis(p-methoxybenzyl)-6,8-diaza-1-hydroxy-2-ethenylbicyclo<2.2.2>octane-5,7-dione 
• 135365-99-0 6,8-bis(p-methoxybenzyl)-6,8-diaza-1-hydroxy-4-methyl-2-ethenylbicyclo<32.1>octane-5,7-dione 
• 117471-63-3 3-((E)-4-Hydroxy-but-2-enyloxy)-1,4-bis-(4-methoxy-benzyl)-piperazine-2,5-dione 
• 117471-56-4 3-[5-(tert-Butyl-diphenyl-silanyloxy)-pent-3-ynyloxy]-1,4-bis-(4-methoxy-benzyl)-piperazine-2,5-dione 

Relevant academic research and scientific papers

Oxidation of α-ylido, β-keto amides to vicinal tricarbonyls. Synthesis of a diketopiperazine precursor of bicyclomycin

The Yoshimura intermediate in the total synthesis of bicyclomycin was prepared by intramolecular addition of an amide to an α,β-diketoamide. The resulting unsymmetrical diketopiperazine was then converted to the diol-ether target.