1447810-66-3

Basic information

• Product Name: (E)-8,8-bis-(phenylsulfonyl)-12-hydroxy-1,14,17,20-tetraoxacyclodocosan-10-en-2-one
• CAS NO: 1447810-66-3
• Molecular Weight: 624.774
• Mol File: 1447810-66-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-8,8-bis-(phenylsulfonyl)-12-hydroxy-1,14,17,20-tetraoxacyclodocosan-10-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-8,8-bis-(phenylsulfonyl)-12-hydroxy-1,14,17,20-tetraoxacyclodocosan-10-en-2-one(1447810-66-3)
• EPA Substance Registry System: (E)-8,8-bis-(phenylsulfonyl)-12-hydroxy-1,14,17,20-tetraoxacyclodocosan-10-en-2-one(1447810-66-3)

Safety Data

• Hazardous Substances Data: 1447810-66-3(Hazardous Substances Data)

Upstream product

• 4224-70-8 6-bromohexanoic acid 
• 112-60-7 Tetraethylene glycol 
• 134179-40-1 tetraethyleneglycol mono(tert-butyldimethylsilyl)ether 
• 14273-90-6 methyl 6-bromohexanoate 
• 218607-15-9 2-[2-(2-tert-butyldimethylsilyloxyethoxy)ethoxy]ethoxyacetaldehyde 
• 1447810-56-1 tert-butyldimethyl-(2-{2-[2-(3-vinyloxiranylmethoxy)ethoxy]ethoxy}ethoxy)silane 
• 1447810-57-2 2-{2-[2-(3-vinyloxiranylmethoxy)ethoxy]ethoxy}ethanol 
• 1447810-50-5 7,7-bis(phenylsulfonyl)heptanoic acid 
• 1447810-49-2 7,7-bis(phenylsulfonyl)-heptanoic acid methyl ester 

Relevant articles and documents

Investigation of the origin and synthetic application of the pseudodilution effect for Pd-catalyzed macrocyclisations in concentrated solutions with immobilized catalysts

Immobilized Pd-complexes allowed macrocyclisations via the Tsuji-Trost-reaction in concentrated solutions. Systematic studies suggest that the origin of this pseudodilution effect is neither film diffusion nor gel diffusion, but the reduction in conformational freedom of intermediates and intramolecular prenucleophile activation. In contrast a pseudodilution effect could not be observed for Sonogashira- and Suzuki-macrocyclisations.