144782-50-3Relevant academic research and scientific papers
Highly stereoselective reduction of acyclic α-sulfinyl ketimines: Synthesis of enantiomerically pure β-aminosulfoxides
Garcia Ruano, Jose L.,Cifuentes, Marta M.,Lorente, Antonio,Rodriguez Ramos, Jesus H.
, p. 4607 - 4618 (2007/10/03)
The DIBAL reduction of enantiomerically pure α-sulfinyl ketimines can be achieved almost completely stereoselectively under ZnX2 catalysis, regardless of the alkyl or aryl substituent at nitrogen and the aliphatic (cyclic or acyclic) or aromati
Synthesis and stereoselective reductions of chiral β-iminosulfoxides
Garcia Ruano,Lorente,Rodriguez
, p. 5637 - 5640 (2007/10/02)
Reaction of chiral non racemic β-ketosulfoxides with amines or condensation of the imine enolates with (-)-menthyl sulfinate yield optically pure β-iminosulfoxides. The second method requires the presence of an excess of MgBr2 in order to avoid
