1447992-75-7Relevant academic research and scientific papers
Probing the utility of palladium complexes supported by morpholine-functionalized N -heterocyclic carbene ligands in Buchwald-Hartwig amination
Wheaton, Craig A.,Stradiotto, Mark
, p. 755 - 762 (2013)
Convenient and high-yielding syntheses of two new morpholine-substituted N-heterocyclic carbene ligands, 1-Ar-3-{2-(4-morpholinyl)phenyl}imidazolidin-2- ylidene (Ar = Dipp, Mes), are described. An investigation of corresponding palladium complexes reveals hemilability, and examples of both monodentate and bidentate coordination are observed. A preliminary investigation of the activity of these palladium complexes for Buchwald-Hartwig amination catalysis is presented.
