Canadian Journal of Chemistry p. 755 - 762 (2013)
Update date:2022-08-05
Topics: Catalysts Utility Palladium Complexes Buchwald-Hartwig amination Probing
Wheaton, Craig A.
Stradiotto, Mark
Convenient and high-yielding syntheses of two new morpholine-substituted N-heterocyclic carbene ligands, 1-Ar-3-{2-(4-morpholinyl)phenyl}imidazolidin-2- ylidene (Ar = Dipp, Mes), are described. An investigation of corresponding palladium complexes reveals hemilability, and examples of both monodentate and bidentate coordination are observed. A preliminary investigation of the activity of these palladium complexes for Buchwald-Hartwig amination catalysis is presented.
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