1448024-46-1Relevant academic research and scientific papers
Palladium-catalyzed selective α-arylation of ortho -bromoacetophenones
Krishna, Jonnada,Reddy, Alavala Gopi Krishna,Satyanarayana, Gedu
supporting information, p. 2103 - 2111 (2014/07/07)
Synthesis of 1-(2-bromophenyl)-2-phenylethanones via an intermolecular Pd-catalyzed α-arylation of 1-(2-bromophenyl)ethanones is presented. The method relies on selective C-H activation (α-arylation) of relatively more reactive external iodo-arenes as cou
A domino palladium catalysis: Synthesis of 7-methyl-5 H -dibenzo[ a, c ][7] annulen-5-ones
Krishna, Jonnada,Gopi Krishna Reddy, Alavala,Satyanarayana, Gedu
supporting information, p. 967 - 972 (2013/07/04)
A domino Pd-catalyzed reaction of 1-(2-bromophenyl)ethanones for the synthesis of novel 7-methyl-5H-dibenzo[a,c][7]annulen-5-ones, a carbon core structure present in colchicinoid natural products, is presented. The reaction is proposed to proceed via intermolecular homobiaryl coupling and intramolecular aldol condensation. Georg Thieme Verlag Stuttgart . New York.
