1448049-58-8

Basic information

• Product Name: N,N-dibenzyl-2,7-dimethyl-3-methylene-6-octenylamine
• Synonyms: N,N-dibenzyl-2,7-dimethyl-3-methylene-6-octenylamine
• CAS NO: 1448049-58-8
• Molecular Weight: 347.544
• Mol File: 1448049-58-8.mol

Chemical Properties

• CAS DataBase Reference: N,N-dibenzyl-2,7-dimethyl-3-methylene-6-octenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dibenzyl-2,7-dimethyl-3-methylene-6-octenylamine(1448049-58-8)
• EPA Substance Registry System: N,N-dibenzyl-2,7-dimethyl-3-methylene-6-octenylamine(1448049-58-8)

Safety Data

• Hazardous Substances Data: 1448049-58-8(Hazardous Substances Data)

Upstream product

• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 57684-32-9 N-((1 H-benzo[d][1,2,3]triazol-1-yl)methyl)-N-benzyl-1-phenylmethanamine 

Relevant articles and documents

A straightforward route to homoallyl-homocrotylamines promoted by a titanium complex

π-Allyltitanium complexes, generated in situ from 1,3-dienes and [Cp2TiH], react with benzotriazole derivatives to give homoallylic amines in good yields. Under similar conditions, triple cascade reactions (allyltitanation followed by cationic 2-aza-Cope rearrangement followed by a second allyltitanation) occur from bis(benzotriazolyl) compounds affording a straightforward route to homoallyl-(E)-homocrotylamines. A theoretical study provides further insight into the factors that govern the selectivity of this sequence of reactions. The titanium-promoted reductive coupling of 1,3-dienes with bis(benzotriazolyl) compounds as substrates led selectively to homoallyl-homocrotylamines through a triple cascade reaction (allyltitanation - cationic 2-aza-Cope rearrangement - allyltitanation). Copyright