1448171-75-2

Upstream product

• 38041-19-9 4-aminotetrahydropyran 
• 945491-50-9 rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III) 

Relevant academic research and scientific papers

[Cp*RhCl2]2-catalyzed ortho-C-H bond amination of acetophenone o-methyloximes with primary N-chloroalkylamines: Convenient synthesis of N-alkyl-2-acylanilines

Rh(iii)-catalyzed aromatic C-H amination of acetophenone o-methyloximes with primary N-chloroalkylamines was developed, and the arylamine products were obtained in up to 92% yield. The reaction probably involves rate-limiting electrophilic C-H bond cleavage (kH/kD = 2).