1448225-58-8Relevant articles and documents
β-arabinofuranosylation using 5- O -(2-quinolinecarbonyl) substituted ethyl thioglycoside donors
Liu, Qiang-Wei,Bin, Hua-Chao,Yang, Jin-Song
, p. 3974 - 3977 (2013)
A new β-stereoselective d- and l-arabinofuranosylation method has been developed employing 5-O-(2-quinolinecarbonyl) substituted arabinosyl ethyl thioglycosides as glycosyl donors. The approach allows a wide range of acceptor substrates to be used; the β-selectivity is good-to-excellent. Stereoselective synthesis of a mannose-capped octasaccharide portion from a mycobacterial cell wall polysaccharide was then carried out to demonstrate the utility of this methodology.