144823-21-2Relevant articles and documents
On the Cycloaddition Approach to Indolocarbazoles
Barry, John F.,Wallace, Timothy W.,Walshe, Nigel D. A.
, p. 12797 - 12806 (2007/10/02)
2,2'-Biindolyl 9 reacts with electron-deficient dienophiles at 100-110 deg C to give low to moderate yields of Michael addition and formal cycloaddition products, with the former predominant; the products derived from 9 and 2-(phenylsulphinyl)maleimides 14 and 15 undergo in situ elimination of benzenesulphenic acid, leading to 2,2'-biindolyl-substituted maleimides which can be efficiently photocyclised into indolocarbazoles.
On the [4 + 2] cycloaddition approach to indolo[2,3-a]carbazoles
Barry, John F.,Wallace, Timothy W.,Walshe, Nigel D. A.
, p. 5329 - 5330 (2007/10/02)
2,2′-Biindolyl 4 reacts with electron-deficient dienophiles at 100-110°C to give low to moderate yields of Michael addition and formal [4 + 2] cycloaddition products, with the former predominant; the products derived from 4 and 2-(phenylsulphinyl)maleimid
A NOVEL SYNTHESIS OF 2,2'-BISINDOLE AND ITS APPLICATION FOR THE SYNTHESIS OF INDOLOCARBAZOLE DERIVATIVES
Somei, Masanori,Kodama, Atsushi
, p. 1285 - 1288 (2007/10/02)
A novel oxidative coupling method of 2-lithio-1-methoxyindole was developed resulting in the formation of 2,2'-bis(1-methoxyindole) (6).Catalytic hydrogenation of 6 produced 2,2'-bisindole (9).Diels-Alder reaction of 9 with dienophiles afforded indolo2,3
