1448461-18-4

Upstream product

• 845734-51-2 5-{[(2S)-2-methylbut-3-en-1-yl]sulfonyl}-1-phenyl-1H-tetrazole 
• 131380-48-8 (E)-4-(t-butyldiphenylsilyl)oxy-2-butenal 
• 6213-88-3 (E)-methyl 3-iodoacrylate 
• 1448461-14-0 tert-butyl{[(2E,4E,6S)-6-methylocta-2,4,7-trien-1-yl]oxy}diphenylsilane 

Relevant academic research and scientific papers

Syntheses of the hexahydroindene cores of indanomycin and stawamycin by combinations of iridium-catalyzed asymmetric allylic alkylations and intramolecular diels-alder reactions

Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki-Miyaura coupling, and an intramolecular Diels-Alder reaction.