144850-02-2Relevant academic research and scientific papers
A novel route to 2-deoxy-2-iodo-D-mannopyranose derivatives
Miljkovic,Djurendic,Vukojevic,Gasi,Csanadi
, p. 251 - 253 (2007/10/02)
This paper reports a formal electrophilic addition of ″hypoiodous acid″ to 3,4,6-tri-O-acetyl-D-glucal and 3,4-di-O-acetyl-6-O-tosyl-D-glucal. Depending on the buffer system used and the pH, a mixture of the 2-deoxy-2-iodo esters together with the corresponding 2-deoxy-2-iodo sugars were obtained. The compounds obtained could be used for the preparation of 2-deoxy sugars or Brigl's anhydrides.
