1448532-91-9Relevant academic research and scientific papers
N-Sulfonyl amidine synthesis via three-component coupling reaction using heterogeneous copper catalyst derived from metal-organic frameworks
Kim, Myeong Jin,Kim, Bo Ram,Lee, Chang Yeon,Kim, Jinho
, p. 4070 - 4073 (2016)
Three-component coupling reaction of terminal alkyne, sulfonyl azide, and amine for the synthesis of N-sulfonyl amidine was developed using heterogeneous Cu@C catalyst, which was generated by pyrolysis of HKUST-1 (Cu3(BTC)2, BTC?=?1,
N-SULFONYL AMIDINE SYNTHESIS VIA THREE-COMPONENT COUPLING REACTION USING HETEROGENEOUS COPPER CATALYST
-
Paragraph 0088-0094; 0096-0102; 0129; 0130; 0142; 0143, (2018/07/31)
The present invention relates to a method of synthesizing N-sulfonyl amidine. More specifically, the present invention relates to the method of synthesizing N-sulfonyl amidine through a three-component coupling reaction using a heterogeneous copper catalyst; and optimization of reaction conditions applied thereto. The method is able to obtain corresponding N-sulfonyl amidine at high yield with respect to various substrates by performing a three-component coupling reaction of terminal alkyne, sulfonyl azide and amine by using a heterogeneous copper catalyst (Cu@C) obtained by pyrolyzing HKUST-1 which is a type of a metal-organic framework, and enables the heterogeneous copper catalyst to be reused at least four or more times without significant loss of catalytic activities since the heterogeneous copper catalyst has structural stability.COPYRIGHT KIPO 2018
Porous metal-organic framework catalyzing the three-component coupling of sulfonyl azide, alkyne, and amine
Yang, Tao,Cui, Hao,Zhang, Changhe,Zhang, Li,Su, Cheng-Yong
, p. 9053 - 9059 (2013/09/02)
The robustly porous metal-organic framework MOF-Cu2I 2(BTTP4) (BTTP4 = benzene-1,3,5-triyl triisonicotinate) was shown to work as an efficiently heterogeneous catalyst for the three-component coupling of sulfonyl azides, alkynes, and
