144889-92-9Relevant academic research and scientific papers
Reactions of dihydrofurylsilanes with O- and N-nucleophiles
Lukevics,Gevorgyan,Borisova
, p. 161 - 163 (2007/10/03)
It was shown that the reaction of 4,5-dilydro-2-furylsilanes with alcohols and lithium N,N-diethylamide leads to substitution of the dihydrofuryl group by the nucleophilic residue. 1997 Plenum Publishing Corporation.
Palladium-catalyzed rearrangement of silanes containing oxygen or halogen α to silicon
Gevorgyan, Vladimir,Borisova, Larisa,Lukevics, Edmunds
, p. 277 - 285 (2007/10/02)
Rearrangements of tetrahydrofuryl- and tetrahydropyranyl-hydrosilanes to oxasilaalkanes, of acetoxymethyl-hydrosilanes to acetoxysilanes, and halogenomethyl-hydrosilanes to halogenosilanes in the presence of palladium catalyst have been studied.The reaction has been shown to proceed more rapidly in tetrahydrofuran and hexane than in benzene or acetonitrile.The progressive replacement of the methyl groups on the silicon atom by phenyl groups slowed down the rearrangement, as did change from five-membered to six-membered heterocycles.
