144923-61-5

Basic information

• Product Name: N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>threonine tert-butyl ester
• Synonyms: N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>threonine tert-butyl ester
• CAS NO: 144923-61-5
• Molecular Weight: 772.031
• Mol File: 144923-61-5.mol

Chemical Properties

• CAS DataBase Reference: N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>threonine tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>threonine tert-butyl ester(144923-61-5)
• EPA Substance Registry System: N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>threonine tert-butyl ester(144923-61-5)

Safety Data

• Hazardous Substances Data: 144923-61-5(Hazardous Substances Data)

Upstream product

• 90-76-6 2-deoxy-2-amino glucose 
• 17460-45-6 tetra-acetyl glucosamine 
• 90176-39-9 2-benzylideneamino-2-deoxy-β-D-glucopyranose 
• 122210-05-3 1,3,4,6-tetra-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranose 
• 19728-63-3 N-benzyloxycarbonyl-L-treonine 
• 52162-39-7 2-(benzylidene)amino-2-deoxy-1,3,4,6-tetra-O-acetyl-β-D-glucopyranose 
• 72289-51-1 tert-butyl (2S,3R)-2-(benzyloxycarbonyl)amino-3-hydroxybutanoate 
• 144923-59-1 ethyl 3,4,6-tri-O-acetyl-2-deoxy-1-thio-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside 

Relevant articles and documents

Synthetic O-glycopeptides as model substrates for glycosyltransferases

A new approach to O-glycopeptides of the glucosamine type is described. N-Urethane protected, peracetylated glucosamine is converted into its 1-thio (1-bromo) derivative and used for glycosylation of a variety of protected serine or threonine derivatives

Enzymatic glycosylation of o-glycopeptides

O-Glycosylation of serine derivatives carried out with N-urethane protected glucosamine yields O-glycopeptides which are regio- and stereoselectively galactosylated with the aid of β-1,4-galactosyltransferase (EC 2.4.1.22).