1449331-10-5

Basic information

• Product Name: (E)-benzyl(4-methylstyryl)sulfane
• Synonyms: (E)-benzyl(4-methylstyryl)sulfane
• CAS NO: 1449331-10-5
• Molecular Weight: 240.369
• Mol File: 1449331-10-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-benzyl(4-methylstyryl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-benzyl(4-methylstyryl)sulfane(1449331-10-5)
• EPA Substance Registry System: (E)-benzyl(4-methylstyryl)sulfane(1449331-10-5)

Safety Data

• Hazardous Substances Data: 1449331-10-5(Hazardous Substances Data)

Upstream product

• 100-53-8 phenylmethanethiol 
• 766-97-2 4-n-methylphenylacetylene 
• 73839-44-8 (Z)-1-[2-bromovinyl]-4-methylbenzene 
• 100-39-0 benzyl bromide 
• 10387-40-3 potassium thioacetate 

Relevant articles and documents

Decarbonylation of Salicylaldehyde Activated by p-Cymene Ruthenium(II) Dimer: Implication for Catalytic Alkyne Hydrothiolation

A stoichiometric C–H activation/decarbonylation of salicylaldehyde by [(η6-p-cymene)RuCl2]2gave a carbonyl derivative [(η6-p-cymene)RuCl(CO)(Ph-O)] (1) without the use of CO gas. A variety of polar phosphines were then incorporated into compound 1 to give new RuIIcationic catalysts, [(η6-p-cymene)Ru(CO)(Ph-O)L]BF4(2–8). These were used to catalyse the hydrothiolation of alkynes with a range of thiols in aqueous THF to give anti-Markovnikov E-linear vinyl sulfides in high yields.