1449335-36-7Relevant articles and documents
Synthesis of novel N-heterocyclic carbene-oxazoline palladium complexes and their applications in suzuki-miyaura cross-coupling reaction
Gu, Peng,Xu, Qin,Shi, Min
, p. 1255 - 1259 (2013/07/11)
A series of novel N-heterocyclic carbene-oxazoline ligands were synthesized in six steps. Palladium complexes were obtained by deprotonation of the benzimidazole salts and subsequent ligation with Pd(OAc)2 in THF. Different types of cyclic bis- and tetrapalladium complexes were achieved by modifying substituent of oxazoline group. The structures of these palladium complexes were characterized by NMR and X-ray diffraction analysis. Catalytic properties of these Pd-complexes were tested by Suzuki-Miyaura cross-coupling reaction. Georg Thieme Verlag Stuttgart. New York.