Welcome to LookChem.com Sign In|Join Free
  • or

577-19-5

Post Buying Request

577-19-5 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
1-Bromo-2-nitrobenzene Manufacturer/High quality/Best price/In stock
Cas No: 577-19-5
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality 1-Bromo-2-Nitrobenzene supplier in China
Cas No: 577-19-5
No Data 1 Metric Ton 30 Metric Ton/Month Simagchem Corporation Contact Supplier
2-Bromonitrobenzene
Cas No: 577-19-5
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
1-bromo-2-nitrobenzene
Cas No: 577-19-5
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Factory Supply 1-Bromo-2-Nitrobenzene
Cas No: 577-19-5
No Data 1 1 Ality Chemical Corporation Contact Supplier
High purity and quality 1- Bromo-2-nitrobenzene
Cas No: 577-19-5
No Data 100 Gram 800 Kilogram/Month Puyang Huicheng Electronic Material Co., Ltd Contact Supplier
1-Bromo-2-nitrobenzene
Cas No: 577-19-5
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
1-bromo-2-nitrobenzene
Cas No: 577-19-5
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 2500 Metric Ton/Month Henan Sinotech Import&Export Corporation Contact Supplier
1-BroMo-2-nitrobenzene
Cas No: 577-19-5
USD $ 1100.0-1500.0 / Metric Ton 5 Metric Ton 10 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier
1-Bromo-2-nitrobenzene
Cas No: 577-19-5
No Data 1 Kilogram 300 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier

577-19-5 Usage

Chemical Properties

white to light yellow crystal powder

Purification Methods

Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 618, 5 IV 728.]
InChI:InChI=1/C6H4BrNO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H

577-19-5 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A11686)  1-Bromo-2-nitrobenzene, 99%    577-19-5 50g 384.0CNY Detail
Alfa Aesar (A11686)  1-Bromo-2-nitrobenzene, 99%    577-19-5 250g 1537.0CNY Detail
Alfa Aesar (A11686)  1-Bromo-2-nitrobenzene, 99%    577-19-5 1000g 2938.0CNY Detail
Aldrich (365424)  1-Bromo-2-nitrobenzene  98% 577-19-5 365424-25G 2,962.44CNY Detail
Aldrich (365424)  1-Bromo-2-nitrobenzene  98% 577-19-5 365424-100G 9,675.90CNY Detail

577-19-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-Bromo-2-nitrobenzene

1.2 Other means of identification

Product number -
Other names o-Nitrophenyl bromide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:577-19-5 SDS

577-19-5Synthetic route

ortho-nitrobenzoic acid
552-16-9

ortho-nitrobenzoic acid

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With bromine; dibromoisocyanuric acid In dichloromethane at 20℃; for 24h; Reagent/catalyst; Concentration; UV-irradiation;100%
With Bromotrichloromethane; trichloroisocyanuric acid; bromine In tetrachloromethane at 10 - 120℃; for 18h; Temperature; Reagent/catalyst; Concentration; Photolysis;97%
With [bis(acetoxy)iodo]benzene; bromine In various solvent(s) for 22h; bromodecarboxylation; Heating; irradiation;51%
4-bromo-3-nitrobenzoic acid
6319-40-0

4-bromo-3-nitrobenzoic acid

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With sulfolane; sodium hydrogencarbonate at 195℃; for 2h;92%
2-nitrobenzenediazonium o-benzenedisulfonamide

2-nitrobenzenediazonium o-benzenedisulfonamide

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution;89%
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution;83%
(2-bromophenyl)boronic acid
244205-40-1

(2-bromophenyl)boronic acid

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate In toluene at 80℃; for 18h; Inert atmosphere;87%
With copper(I) oxide; ammonium hydroxide; oxygen; sodium nitrite In water at 25℃; for 36h;44%
C14H10Br2F3IO4S

C14H10Br2F3IO4S

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With sodium nitrite In 1,2-dichloro-ethane at 20 - 80℃; Schlenk technique;85%
2-nitro-aniline
88-74-4

2-nitro-aniline

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With tert.-butylnitrite; tetrabutylammomium bromide; copper(I) bromide; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Reagent/catalyst; Time; Solvent;83%
With potassium nitrite; hydrogen bromide; dimethyl sulfoxide In water at 35℃; for 0.25h;78%
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide In acetonitrile at 20℃; for 1h;76%
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With aluminum oxide; copper(I) bromide In various solvent(s) at 150℃; for 8h;80%
2-nitrophenylboronic acid
5570-19-4

2-nitrophenylboronic acid

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With sodium nitrite In acetonitrile at 80℃; for 20h; Sealed tube;80%
nitrobenzene
98-95-3

nitrobenzene

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
Stage #1: nitrobenzene With acetic acid at 0℃;
Stage #2: With bromine at 20℃; for 12h;
78.9%
With bromine; acetic acid at 0 - 20℃; for 12h;78.9%
With hydrogen bromide; dimethyl sulfoxide for 21h; Ambient temperature;67%
bromobenzene
108-86-1

bromobenzene

A

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

B

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
With nitric acid at 50℃; for 3h;A 20.9%
B 78.2%
With Iron(III) nitrate nonahydrate; phosphorus pentoxide In neat (no solvent) at 20℃; for 6h; Milling; Green chemistry; Overall yield = 93 percent;A 25%
B 68%
With thionyl chloride; bismuth subnitrate In dichloromethane at 20℃; for 9h;A 18%
B 60%
2-bromoaniline
615-36-1

2-bromoaniline

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In 1,2-dichloro-ethane for 10h; Reflux;74%
Stage #1: 2-bromoaniline With sulfuric acid In 1,4-dioxane at -15℃;
Stage #2: With sodium nitrite In 1,4-dioxane at -15℃;
2-nitrobenzenediazonium tetrafluoroborate
365-33-3

2-nitrobenzenediazonium tetrafluoroborate

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With N-Bromosuccinimide; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction;61%
1,2-Dinitrobenzene
528-29-0

1,2-Dinitrobenzene

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
Stage #1: 1,2-Dinitrobenzene With perchloric acid; sulfuric acid; sodium nitrite In water; ethyl acetate Electrochemical reaction;
Stage #2: With hydrogen bromide; copper In water Electrochemical reaction;
60%
2-nitrophenyl trifluoromethanesulfonate
132993-22-7

2-nitrophenyl trifluoromethanesulfonate

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With tetrabutylammomium bromide In toluene for 48h; Heating;48%
o-nitrophenylhydrazine hydrochloride
6293-87-4

o-nitrophenylhydrazine hydrochloride

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With boron tribromide; dimethyl sulfoxide at 80℃; for 1h;45%
3-Bromo-4-nitrobenzoic acid
101420-81-9

3-Bromo-4-nitrobenzoic acid

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver(I) acetate In acetonitrile at 100℃; for 24h;43%
2-bromo-N,N-dimethylaniline
698-00-0

2-bromo-N,N-dimethylaniline

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With tert.-butylhydroperoxide; ammonium iodide; water In dimethyl sulfoxide at 90℃; for 6h; Sealed tube;38%
bromobenzene
108-86-1

bromobenzene

nitro acetate
591-09-3

nitro acetate

A

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

B

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
With acetic anhydride at 0℃;
bromobenzene
108-86-1

bromobenzene

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
beim Nitrieren;
With nitric acid; acetic anhydride; H5PV2Mo10O40(1,11) for 1h; Heating;62 % Chromat.
3-bromo-4-nitroaniline
40787-96-0

3-bromo-4-nitroaniline

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With ethanol; mixture of gaseous nitrogen oxides
bromobenzene
108-86-1

bromobenzene

nitro acetate
591-09-3

nitro acetate

acetic anhydride
108-24-7

acetic anhydride

A

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

B

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
at 25℃;
at 0℃;
silver(I) o-nitrobenzoate
72247-99-5

silver(I) o-nitrobenzoate

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
With tetrachloromethane; bromine
bromobenzene
108-86-1

bromobenzene

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

2-bromo-1-chlorobenzene
694-80-4

2-bromo-1-chlorobenzene

C

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

D

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
With Nitryl chloride; trifluoroacetic acid at 20℃; for 8h; Product distribution; Mechanism;
bromobenzene
108-86-1

bromobenzene

A

3-Bromonitrobenzene
585-79-5

3-Bromonitrobenzene

B

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

C

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
With nitric acid In water at 25℃;A 0.4 % Chromat.
B 36.3 % Chromat.
C 62.8 % Chromat.
With dinitrogen tetraoxide; N,N,N,N-tetraethylammonium tetrafluoroborate In sulfolane at 30℃; electrochemical process; Yield given. Yields of byproduct given;
With nitric acid; ytterbium(III) triflate In 1,2-dichloro-ethane for 12h; Heating; Title compound not separated from byproducts;
bromine
7726-95-6

bromine

1,2-Dinitrobenzene
528-29-0

1,2-Dinitrobenzene

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

Conditions
ConditionsYield
at 180℃;
ethyl bromide
74-96-4

ethyl bromide

bromine
7726-95-6

bromine

nitrobenzene
98-95-3

nitrobenzene

A

3-Bromonitrobenzene
585-79-5

3-Bromonitrobenzene

B

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

C

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
Kinetics; Beschuss mit langsamen Neutronen;
bromobenzene
108-86-1

bromobenzene

nitric acid
7697-37-2

nitric acid

A

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

B

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
Product distribution;
aluminium trichloride
7446-70-0

aluminium trichloride

bromobenzene
108-86-1

bromobenzene

dinitrogen tetraoxide
10544-72-6

dinitrogen tetraoxide

A

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

B

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
ConditionsYield
at 0 - 10℃;
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

nitric acid
7697-37-2

nitric acid

A

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

B

bromoiodonitrobenzene

bromoiodonitrobenzene

Conditions
ConditionsYield
at -10℃;
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

N-(2-bromophenyl)hydroxylamine
35758-75-9

N-(2-bromophenyl)hydroxylamine

Conditions
ConditionsYield
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;100%
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; Inert atmosphere;100%
With methyldiazene In acetonitrile at 28℃; for 3.5h; Irradiation; Sealed tube; Inert atmosphere;95%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With Cu(Ph3P)3F In N,N-dimethyl-formamide at 170℃; for 5h;100%
trans-geranyl bromide
6138-90-5

trans-geranyl bromide

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

1-((E)-3,7-Dimethyl-octa-2,6-dienyl)-2-nitro-benzene

1-((E)-3,7-Dimethyl-octa-2,6-dienyl)-2-nitro-benzene

Conditions
ConditionsYield
Stage #1: 2-nitrophenyl bromide With phenyllithium In tetrahydrofuran at -78℃; for 0.0833333h;
Stage #2: trans-geranyl bromide With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at -78℃; for 3h;
100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

benzyl bromide
100-39-0

benzyl bromide

2-nitrodiphenylmethane
5840-40-4

2-nitrodiphenylmethane

Conditions
ConditionsYield
Stage #1: 2-nitrophenyl bromide With phenyllithium In tetrahydrofuran at -78℃; for 0.0833333h;
Stage #2: benzyl bromide With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at -78℃; for 3h;
100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

C14H13NO2

C14H13NO2

Conditions
ConditionsYield
Stage #1: 2-nitrophenyl bromide With phenyllithium In tetrahydrofuran at -78℃; for 0.0833333h;
Stage #2: 2-methylbenzyl bromide With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at -78℃; for 3h;
100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

prenyl bromide
870-63-3

prenyl bromide

1-(3-methylbut-2-en-1-yl)-2-nitrobenzene
421571-68-8

1-(3-methylbut-2-en-1-yl)-2-nitrobenzene

Conditions
ConditionsYield
Stage #1: 2-nitrophenyl bromide With phenyllithium In tetrahydrofuran at -78℃; for 0.0833333h;
Stage #2: prenyl bromide With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at -78℃; for 3h;
100%
Stage #1: 2-nitrophenyl bromide With phenyllithium In tetrahydrofuran at -78℃;
Stage #2: prenyl bromide With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at -78℃; for 3h;
100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

8-methoxy-naphthalen-1-ylboronic acid

8-methoxy-naphthalen-1-ylboronic acid

8-methoxy-1-(2'-nitrophenyl)naphthalene
683764-60-5

8-methoxy-1-(2'-nitrophenyl)naphthalene

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 100℃; for 3.5h; Suzuki-Miyaura coupling reaction;100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

(S)-2,2'-diamino-1,1'-binaphthalene
18531-95-8

(S)-2,2'-diamino-1,1'-binaphthalene

(S)-(+)-N2,N2'-bis(2-nitrophenyl)-1,1'-binaphthalenyl-2,2'-diamine

(S)-(+)-N2,N2'-bis(2-nitrophenyl)-1,1'-binaphthalenyl-2,2'-diamine

Conditions
ConditionsYield
With DPE-Phos; caesium carbonate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 80℃; for 48h;100%
With caesium carbonate; bis[2-(diphenylphosphino)phenyl] ether; tris(dibenzylideneacetone)dipalladium (0) In toluene at 80℃; for 48h;100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

10-hexyl-3,7-bis(4,4,5,5-tetramethyl-[1,3,2]-dioxaborolan-2-yl)-10H-phenothiazine
405198-30-3

10-hexyl-3,7-bis(4,4,5,5-tetramethyl-[1,3,2]-dioxaborolan-2-yl)-10H-phenothiazine

10-hexyl-3,7-bis(2-nitrophenyl)-10H-phenothiazine

10-hexyl-3,7-bis(2-nitrophenyl)-10H-phenothiazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,2-dimethoxyethane; water at 90℃; for 18h; Suzuki coupling;100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

5-chloroanthranilic acid
635-21-2

5-chloroanthranilic acid

5-Chloro-2-(2-nitro-phenylamino)-benzoic acid
97027-31-1

5-Chloro-2-(2-nitro-phenylamino)-benzoic acid

Conditions
ConditionsYield
With copper; potassium carbonate In pentan-1-ol at 150℃; Ullman coupling;100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

phenylboronic acid
98-80-6

phenylboronic acid

2-nitrobiphenyl
86-00-0

2-nitrobiphenyl

Conditions
ConditionsYield
With potassium carbonate In water; isopropyl alcohol at 100℃; for 10h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With potassium phosphate; second generation phosphine dendrimer-stabilized palladium In 1,4-dioxane for 20h; Suzuki coupling; Heating;99%
With potassium phosphate tribasic heptahydrate In 1,4-dioxane for 20h; Suzuki coupling; Reflux;99%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

N-butylamine
109-73-9

N-butylamine

o-Nitro-N-n-butylaminobenzene
42896-66-2

o-Nitro-N-n-butylaminobenzene

Conditions
ConditionsYield
In dimethyl sulfoxide at 80℃;100%
In dimethyl sulfoxide at 80℃;100%
In dimethyl sulfoxide
4-dibenzofurylboronic acid
100124-06-9

4-dibenzofurylboronic acid

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

4-(2-nitrophenyl)dibenzo[b,d]furan
1246308-80-4

4-(2-nitrophenyl)dibenzo[b,d]furan

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene for 12h; Reflux;100%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 24h; Reflux;99.7%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 3h; Reflux;98%
4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)pyrrole-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester
942070-38-4

4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)pyrrole-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

1-tert-butyl 2-methyl 4-(2-nitrophenyl)-1H-pyrrole-1,2-dicarboxylate

1-tert-butyl 2-methyl 4-(2-nitrophenyl)-1H-pyrrole-1,2-dicarboxylate

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In water; butan-1-ol at 35℃; for 16h; Suzuki Coupling; Sealed tube; Inert atmosphere;100%
4-methyl-6-(methyloxy)-3-pyridinamine
6635-91-2

4-methyl-6-(methyloxy)-3-pyridinamine

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

6-methoxy-4-methyl-N-(2-nitrophenyl)pyridin-3-amine

6-methoxy-4-methyl-N-(2-nitrophenyl)pyridin-3-amine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium tert-pentoxide; XPhos In 1,4-dioxane at 110℃;100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

N2,3-dimethylpyridine-2,5-diamine

N2,3-dimethylpyridine-2,5-diamine

N2,3-dimethyl-N5-(2-nitrophenyl)pyridine-2,5-diamine

N2,3-dimethyl-N5-(2-nitrophenyl)pyridine-2,5-diamine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium tert-pentoxide; XPhos In 1,4-dioxane at 110℃;100%
1-methyl-1H-indazol-5-amine
50593-24-3

1-methyl-1H-indazol-5-amine

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

1-methyl-N-(2-nitrophenyl)-1H-indazol-5-amine

1-methyl-N-(2-nitrophenyl)-1H-indazol-5-amine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); XPhos In 1,4-dioxane at 110℃;100%
(S)-2,2',3,3'-tetrahydro-1,1'-spirobi-[indene]-7,7'-diamine

(S)-2,2',3,3'-tetrahydro-1,1'-spirobi-[indene]-7,7'-diamine

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

(S)-N7,N7'-bis(2-nitrophenyl)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene]-7,7'-diamine

(S)-N7,N7'-bis(2-nitrophenyl)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene]-7,7'-diamine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; bis[2-(diphenylphosphino)phenyl] ether In toluene at 80℃; for 48h; Buchwald-Hartwig Coupling; Inert atmosphere;100%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

2-bromoaniline
615-36-1

2-bromoaniline

Conditions
ConditionsYield
With hydrogen In tetrahydrofuran; water at 120℃; under 22502.3 Torr; for 4h; Autoclave;99%
With hydrazine In ethanol at 80℃; for 0.333333h; Catalytic behavior; chemoselective reaction;99.6%
With hydrogen In water at 120℃; under 15001.5 Torr; for 5h; Green chemistry; chemoselective reaction;99%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

methylamine
74-89-5

methylamine

2-nitro-N-methylaniline
612-28-2

2-nitro-N-methylaniline

Conditions
ConditionsYield
With copper In water at 100℃; for 12h; Ullmann reaction;99.5%
With ethanol at 150℃; unter Druck;
In ethanol at 150℃;
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4'-chloro-2-nitrobiphenyl
6271-80-3

4'-chloro-2-nitrobiphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 5h; Inert atmosphere;99%
With tetrabutylammomium bromide; sodium acetate; C50H63Cl2N3Pd; sodium carbonate In ethanol; water at 90℃; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Suzuki-Miyaura Coupling;99.2%
With C30H24N3OPPd; potassium carbonate In tetrahydrofuran; N,N-dimethyl-formamide for 1h; Suzuki Coupling; Reflux;75%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

2-Chloroaniline
95-51-2

2-Chloroaniline

N-(2-chlorophenyl)-N-(2-nitrophenyl)amine
74002-26-9

N-(2-chlorophenyl)-N-(2-nitrophenyl)amine

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃;99%
With sodium acetate; nitrobenzene
With copper; potassium carbonate at 160℃;
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

trimethyl((2-nitrophenyl)ethynyl)silane
75867-47-9

trimethyl((2-nitrophenyl)ethynyl)silane

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine for 4h; Inert atmosphere;99%
With triethylamine; bis-triphenylphosphine-palladium(II) chloride at 20℃; for 48h;96%
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide at 20℃;89%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-methyl-2'-nitrobiphenyl
70680-21-6

4-methyl-2'-nitrobiphenyl

Conditions
ConditionsYield
With palladium diacetate; 4-Ph2P-C6H4-2-N-glucosamine; sodium carbonate In tetrahydrofuran; ethanol; water at 60℃; for 18h;99%
With caesium carbonate; [PdCl(NNCNHC-nBu)]BF4 In water; N,N-dimethyl-formamide at 80℃; for 0.5h; Suzuki-Miyaura reaction;98%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane at 100℃; for 12h;97%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

2-farnesylnitrobenzene

2-farnesylnitrobenzene

Conditions
ConditionsYield
Stage #1: 2-nitrophenyl bromide With phenyllithium In tetrahydrofuran at -78℃; for 0.0833333h;
Stage #2: farnesyl bromide With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at -78℃; for 3h;
99%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

3-methoxyphenylboronic acid
10365-98-7

3-methoxyphenylboronic acid

2-(3-Methoxyphenyl)nitrobenzene
92017-95-3

2-(3-Methoxyphenyl)nitrobenzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 5h; Inert atmosphere;99%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,2-dimethoxyethane at 110℃; for 5h;93%
With potassium carbonate; Pd(PPh3)4 In 1,2-dimethoxyethane; water; ethyl acetate
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water at 90℃; for 12h; Inert atmosphere;
1,1'-biphenyl-2,2'-diamine
1454-80-4

1,1'-biphenyl-2,2'-diamine

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

N,N'-bis-(2-nitro-phenyl)-biphenyl-2,2'-diyldiamine
860590-00-7

N,N'-bis-(2-nitro-phenyl)-biphenyl-2,2'-diyldiamine

Conditions
ConditionsYield
With caesium carbonate; bis[2-(diphenylphosphino)phenyl] ether; tris(dibenzylideneacetone)dipalladium (0) In toluene at 80℃; for 48h;99%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

2-nitrobiphenyl
86-00-0

2-nitrobiphenyl

Conditions
ConditionsYield
With sodium hydroxide; palladium diacetate at 60℃; for 2h; Hiyama reaction;99%
With tetrabutyl ammonium fluoride; caesium carbonate In 1,4-dioxane; water at 80℃; for 7h; Hiyama Coupling; chemoselective reaction;83%
With trans-[1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene]PdCl2(NC5H5); sodium hydroxide In 1,4-dioxane; water at 80℃; for 16h; Hiyama cross-coupling;> 99 %Chromat.
With cis-{1-benzyl-3-methyl-4-phenyl-1,2,3-triazol-5-ylidene}PdI2(PPh3)*acetonitrile; sodium hydroxide In 1,4-dioxane; water at 80℃; for 4h; Catalytic behavior; Reagent/catalyst; Hiyama Coupling;84 %Chromat.
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

N-methylaniline
100-61-8

N-methylaniline

2-nitro-N-methyl-N-phenylaniline
52997-62-3

2-nitro-N-methyl-N-phenylaniline

Conditions
ConditionsYield
With caesium carbonate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 85℃; for 20.25h;99%
With C31H38N5P; caesium carbonate; bis(dibenzylideneacetone)-palladium(0) In tert-Amyl alcohol at 100℃; Inert atmosphere;94.33%
With C31H38N5P; caesium carbonate; bis(dibenzylideneacetone)-palladium(0) In tert-Amyl alcohol at 100℃; Buchwald-Hartwig Coupling; Inert atmosphere;94.33%
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 577-19-5