1449519-96-3Relevant articles and documents
Combined C-H functionalization/O-H insertion reaction to form tertiary β-alkoxy substituted β-aminophosphonates catalyzed by [Cu(MeCN) 4]PF6
Cai, Yan,Lu, Yuchen,Yu, Chengbin,Lyu, Hairong,Miao, Zhiwei
, p. 5491 - 5499 (2013/09/02)
The copper-catalyzed C-H functionalization/O-H insertion reaction of α-diazophosphonates with alcohols has been developed with iodine as an additive. In order to understand this reaction, we present here a possible mechanism for the combined reaction. This process provides straightforward access to tertiary β-alkoxy substituted β-aminophosphonate derivatives with moderate to good yields. The Royal Society of Chemistry.