1449549-35-2Relevant academic research and scientific papers
Hydrophenoxylation of internal alkynes catalysed with a heterobimetallic Cu-NHC/Au-NHC system
Lazreg, Fa?ma,Guidone, Stefano,Gómez-Herrera, Alberto,Nahra, Fady,Cazin, Catherine S. J.
supporting information, p. 2439 - 2444 (2017/03/08)
A straightforward method for the hydrophenoxylation of internal alkynes, using N-heterocyclic carbene-based copper(i) and gold(i) complexes, is described. The heterobimetallic catalytic system proceeds via dual activation of the substrates to afford the d
Pd-catalyzed addition of boronic acids to ynol ethers: A highly regio- and stereoselective synthesis of trisubstituted vinyl ethers
Bai, Yihui,Yin, Jing,Kong, Wei,Mao, Mengyi,Zhu, Gangguo
supporting information, p. 7650 - 7652 (2013/09/02)
A Pd-catalyzed addition of boronic acids to ynol ethers has been realized, delivering trisubstituted vinyl ethers in good yields with perfect control of the regio- and stereoselectivity. The reaction proceeds under mild conditions and exhibits excellent functional group compatibility. Moreover, the resultant products can be converted into pentasubstituted benzenes via the tandem Diels-Alder/aromatization reaction. The Royal Society of Chemistry.
