1449549-84-1Relevant articles and documents
Monodentate chiral N-heterocyclic carbene-palladium-catalyzed asymmetric Suzuki-Miyaura and Kumada coupling
Wu, Linglin,Salvador, Alvaro,Ou, Arnold,Shi, Ming Wen,Skelton, Brian W.,Dorta, Reto
, p. 1215 - 1220 (2013)
N-Heterocyclic carbene ligands derived from C2-symmetric diamine with naphthyl side chains are introduced as chiral monodentate ligands, and their palladium complexes (NHC)Pd(cin)Cl are prepared. These compounds exist as a mixture of diastereomers, and the palladium complexes can be successfully separated. When used in the asymmetric Suzuki-Miyaura and Kumada coupling, chiral biaryls can be obtained in high yield and moderate selectivity. Georg Thieme Verlag Stuttgart New York.