998-93-6

Basic information

• Product Name: 4-BROMOHEPTANE
• Synonyms: 4-bromo-heptan;Heptane, 4-bromo-;Heptane,4-bromo-;4-BROMOHEPTANE;4-Bromoheptane,tech.85%;4-BROMOHEPTANE: TECH., 85%;4-BroMoheptane, tech. 85%, reMainder Mainly 3-broMoheptane
• CAS NO: 998-93-6
• Molecular Formula: C₇H₁₅Br
• Molecular Weight: 179.1
• EINECS: 213-653-3
• Mol File: 998-93-6.mol
• Article Data: 6

Chemical Properties

• Melting Point: -4.55°C (estimate)
• Boiling Point: 60-62°C 18mm
• Flash Point: 40°C
• Appearance: /
• Density: 1,14 g/cm3
• Vapor Pressure: 2.18mmHg at 25°C
• Refractive Index: 1.4500
• Water Solubility: Miscible with carbon tetrachloride, chloroform and benzene. Immiscible with water.
• BRN: 1697144
• CAS DataBase Reference: 4-BROMOHEPTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMOHEPTANE(998-93-6)
• EPA Substance Registry System: 4-BROMOHEPTANE(998-93-6)

Safety Data

• Hazard Codes: Xn
• Statements: 10-22
• Safety Statements: 23-24/25
• RIDADR: 1993
• TSCA: Yes
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 998-93-6(Hazardous Substances Data)

Usage

Uses

4-Bromoheptane is used in the preparation of 4-nitro-heptane by reacting with sodium nitrite as a reagent.

InChI:InChI=1/C7H15Br/c1-3-5-7(8)6-4-2/h7H,3-6H2,1-2H3

Upstream product

• 589-82-2 heptan-3-ol 
• 142-82-5 n-heptane 
• 589-55-9 heptan-4-ol 
• 10035-10-6 hydrogen bromide 
• 40754-97-0 N-4-heptylbenzamide 
• 7789-69-7 phosphorus pentabromide 

Downstream Products

• 100532-71-6 4-(1-propyl-butyl)-resorcinol 
• 257292-10-7 methyl 4-amino-3-(4-heptyloxy)benzoate 
• 142-82-5 n-heptane 
• 40887-25-0 N'-phenylhydrazine carboxylic acid 1-propylbutyl ester 
• 1542235-39-1 N-(heptan-4-yl)cyclohexanecarboxamide 
• 1108792-73-9 N-[(1S,2R)-1-benzyl-2-hydroxy-3-{[3-(trifluoromethyl)benzyl]amino}propyl]-1-oxo-2-(1-propylbut-1-yl)-1,2-dihydroisoquinolin-5-carboxamide hydrochloride 
• 1108792-60-4 N-[(1S,2R)-1-benzyl-2-hydroxy-3-{[3-(trifluoromethyl)benzyl]amino}propyl]-1-oxo-2-(1-propylbut-1-yl)-1,2-dihydroisoquinolin-5-carboxamide 
• 116454-37-6 2-methylheptanoic acid 
• 124-07-2 Octanoic acid 
• 1449549-84-1 1S,2S-N,N′-bis[2-(4-heptyl)-naphthalen-1-yl]-1,2-diphenylethane-1,2-diamine 
• 1138320-57-6 N'-phenylhydrazinecarbodithioic acid 1-propylbutyl ester 
• 99-66-1 valproic acid 
• 104463-51-6 5,5-dipropyl-1-pyrroline 1-oxide 
• 949536-20-3 C₂₄H₃₂FN₃O₂ 

Relevant articles and documents

Rapid oxidation of 1,2-diols, α-hydroxyketones and some alcohols using N-bromosuccinimide in ionic liquid

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Direct bromination and iodination of non-activated alkanes by hypohalite reagents

The direct functionalisation of alkanes through bromination and iodination has been successfully achieved. The combination of stoichiometric mixtures of elemental halogen and sodium alkoxides leads to the formation of alkyl hypobromites and hypoiodites as reagents. The halogenation occurs without external photostimulation under thermal reaction conditions. Georg Thieme Verlag Stuttgart.

Bromination of Alcohols by Boron Tribromide

Boron tribromide was used as a brominating agent for the conversion of alcohols to bromides.Tertiary alcohols were more reactive than secondary alcohols which were more reactive than primary alcohols.