Cas 1450897-59-2,4-(4-(methylthio)phenyl)pyrimidine

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Check Digit Verification of cas no

The CAS Registry Mumber 1450897-59-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,5,0,8,9 and 7 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1450897-59:
(9*1)+(8*4)+(7*5)+(6*0)+(5*8)+(4*9)+(3*7)+(2*5)+(1*9)=192
192 % 10 = 2
So 1450897-59-2 is a valid CAS Registry Number.

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1450897-59-2Relevant academic research and scientific papers

Investigation of the scope and mechanism of copper catalyzed regioselective methylthiolation of aryl halides Dedicated to Professor Dr. Irina Beletskaya

Joseph, P.J. Amal,Priyadarshini,Kantam, M. Lakshmi,Sreedhar

supporting information, p. 8276 - 8283 (2013/09/02)

Methylthiolation of structurally diverse aryl halides was accomplished under fluoride free conditions using catalytic amounts of CuI, and DMSO as the methylthiolation source. Optimization studies unveiled several varieties of promoters among which Zn(OAc)2 was found ideal. The analogous reaction with DMSO-d6 afforded corresponding deuterated aryl methyl thioether with 99% purity. Mechanistic studies revealed CuSMe as the active methylthiolation agent.

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