145091-66-3Relevant academic research and scientific papers
Br?nsted acid-catalysed conjugate addition of photochemically generated α-amino radicals to alkenylpyridines
Hepburn, Hamish B.,Melchiorre, Paolo
supporting information, p. 3520 - 3523 (2016/03/04)
The conjugate addition of α-amino radicals to alkenylpyridines has been accomplished by the synergistic merger of Br?nsted acid and visible light photoredox catalysis. Key to reaction development was the protonation of the alkenylpyridines that transientl
Catalytic, oxidant-free, direct olefination of alcohols using Wittig reagents
Khaskin,Milstein
supporting information, p. 9002 - 9005 (2015/05/27)
Reported here is the catalytic, acceptorless coupling of alcohols with in situ generated, non-stabilized phosphonium ylides to form olefins as major products. The reaction uses low catalyst loadings and does not require added oxidants. Hydrogenation of the product is minimized and the reaction leads to Z (aliphatic) or E (benzylic) stereospecificity.
