145098-65-3Relevant academic research and scientific papers
Intramolecular Diels-Alder Reactions of Silyl Acetal Trienes. Dienophile-controlled Cycloadditions of 'Matched' and 'Unmatched' Dimethylated Substrates
Craig, Donald,Reader, John C.
, p. 6165 - 6168 (1992)
Thermal intramolecular Diels-Alder reaction of a mixture of silyl acetal trienes 5 and 6 followed by HF-mediated removal of the silicon tether gives in high overall yield the cyclic diol-esters 9 and 10.Compound 10 is converted selectively under acid cata
Intramolecular Diels-Alder Reactions of Silyl Acetal-tethered Trienes
Ainsworth, Peter J.,Craig, Donald,Reader, John C.,Slawin, Alexandra M. Z.,White, Andrew J. P.,Williams, Dawid J.
, p. 11601 - 11622 (2007/10/02)
The synthesis and intramolecular Diels-Alder reactions of a series of silyl acetal-tethered trienes 4-9 are described.The cycloadditions show complete regioselectivity, and in all but one case give exclusively cis-fused bicyclic products.The selectivities
