Intramolecular Diels-Alder Reactions of Silyl Acetal Trienes. Dienophile-controlled Cycloadditions of 'Matched' and 'Unmatched' Dimethylated Substrates

DOI: 10.1016/S0040-4039(00)60033-3

Source and publish data:

Tetrahedron Letters p. 6165 - 6168 (1992)

Update date:2022-09-26

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Authors:

Craig, Donald

Reader, John C.

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Article abstract of DOI:10.1016/S0040-4039(00)60033-3

Thermal intramolecular Diels-Alder reaction of a mixture of silyl acetal trienes 5 and 6 followed by HF-mediated removal of the silicon tether gives in high overall yield the cyclic diol-esters 9 and 10.Compound 10 is converted selectively under acid cata

Full text of DOI:10.1016/S0040-4039(00)60033-3

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