1451044-91-9Relevant academic research and scientific papers
A convenient synthesis of α-substituted β,γ-unsaturated ketones and esters via the direct addition of substituted allylic zinc reagents prepared by direct insertion
Saemann, Christoph,Knochel, Paul
, p. 1870 - 1876 (2013)
A practical and convenient procedure for the synthesis of α-substituted β,γ-unsaturated ketones and esters has been developed. Substituted allylic zinc reagents, prepared via direct metal insertion in substituted allylic halides, react readily with a broad range of acid chlorides and chloroformates furnishing the corresponding α-substituted β,γ-unsaturated ketones and esters in high yield and perfect regioselectivity. Georg Thieme Verlag Stuttgart · New York.
