1451060-58-4Relevant academic research and scientific papers
Unexpected behaviour of 6-cyanopurines towards secondary amines
Al-Azmi, Amal,Kumari, K. Anita
, p. 1301 - 1309 (2013)
Reaction of 6-cyanopurines with excess dimethylamine and excess piperidine at room temperature or by reflux-respectively-yielded a mixture of 6-purinecarboximidamides and N,N-dialkylpurines or piperidin-1-yl(purin-6-yl) methanimine and (piperidin-1-yl)-9H-purine, respectively. 6- Purinecarboximidamides were initially formed from the reaction, whereas N,N-dialkylpurines were detected in the mixture 30 min afterward. Both purines appeared to be generated from different mechanistic pathways.
