1451064-02-0Relevant articles and documents
Aryl radical formation by copper(I) photocatalyzed reduction of diaryliodonium salts: NMR Evidence for a CuII/CuI mechanism
Baralle, Alexandre,Fensterbank, Louis,Goddard, Jean-Philippe,Ollivier, Cyril
, p. 10809 - 10813 (2013)
Photocatalyzed reduction of diaryliodonium salts was achieved by using [Cu(dpp)2][PF6] as a photoactive complex and DIPEA as a reductive quench. The application of a copper catalyst allows the generation of aryl radicals under mild conditions and maintains their reactivity for C-C bond formation processes.