61358-25-6

Basic information

• Product Name: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate
• Synonyms: BIS(4-TERT-BUTYLPHENYL)IODONIUM HEXAFLUOROPHOSPHATE; Iodonium bis[4-(1,1-dimethylethyl)phenyl] Hexafluorophospha;Bis(4-t-butyl phenyl)iodonium hexafluorophosphate;HRcure-9388;Bis(4-(tert-butyl);iodonium hexafluorophosphate(V);bis(4-tert-butylphenyl)iodanium:hexafluorophosphate;iodonium salt
• CAS NO: 61358-25-6
• Molecular Formula: C₂₀H₂₆I*F₆P
• Molecular Weight: 538.29
• Product Categories: Diphenyliodonium Compounds;Functional Materials;Iodonium Sulfonium & Oxonium Compounds;Photopolymerization Initiators;Photoinitiator
• Mol File: 61358-25-6.mol
• Article Data: 1

Chemical Properties

• Melting Point: 174 °C
• Appearance: /
• Density: 1.57g/cm3 at 21℃
• Vapor Pressure: 0Pa at 25℃
• Solubility: soluble in Ethanol
• BRN: 5721061
• CAS DataBase Reference: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate(61358-25-6)
• EPA Substance Registry System: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate(61358-25-6)

Safety Data

• Hazard Codes: C
• Statements: 36/37/38-34
• Safety Statements: 26-36-45-36/37/39
• RIDADR: UN 1759 8 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 61358-25-6(Hazardous Substances Data)

Usage

Uses

Bis(4-(tert-butyl)phenyl)iodonium hexafluorophosphate(V) is an organic catalyst used for the photoinduced thermal polymerization reactions.

InChI:InChI=1/C20H26I.F6P/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6;1-7(2,3,4,5)6/h7-14H,1-6H3;/q+1;-1

Upstream product

• 253185-03-4 tert-butylbenzene 

Downstream Products

• 160001-85-4 1-(tert-butyl)-4-(trifluoromethyl)benzene 
• 23055-77-8 4'-chloro-4-bromo-biphenyl 
• 1451064-02-0 ethyl 2-(4-tert-butylbenzyl) acrylate 
• 253185-03-4 tert-butylbenzene 
• 358-63-4 tris(2,2,2-trifluoroethyl) phosphate 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 1428647-08-8 bis(2,2,2-trifluoroethyl) tert-butylphenylphosphonate 
• 172422-37-6 Phenyl-phosphonic acid bis-(2,2,2-trifluoro-ethyl) ester 
• 462-06-6 fluorobenzene 
• 591-50-4 iodobenzene 
• 22904-43-4 4-tert-Butyl-phenylradikal 
• 100-66-3 methoxybenzene 
• 35779-04-5 tert-Butylphenyliodoniumradikalkation 

Relevant articles and documents

Photoredox-Catalyzed Cascade Reactions Involving Aryl Radical: Total Synthesis of (±)-Norascyronone A and (±)-Eudesmol

Herein, we have developed two types of photoredox-catalyzed cascade reactions using diaryliodonium salts for the concise synthesis of norascyronone A and β-eudesmol. A rationally designed photoredox-catalyzed arylation/cyclization/Friedel-Crafts cascade reaction of enone was exploited to generate the norascyronone polycyclic skeleton. A visible-light-induced radical cyclization/acyloxy-migration reaction was explored to forge the decalin skeleton of eudesmol, and mechanistic studies indicated the reaction was initiated by one-electron oxidation of the enol ester.