1451210-95-9Relevant academic research and scientific papers
Rhodium(iii)-catalyzed ortho-olefination of aryl phosphonates
Chary, Bathoju Chandra,Kim, Sunggak
supporting information, p. 6879 - 6882 (2013/10/08)
Rhodium(iii)-catalyzed C-H olefination of aryl phosphonic esters is reported for the first time. In this mild and efficient process, the phosphonic ester group is utilized successfully as a new directing group. In addition, mono-olefination for aryl phosphonates is observed using a phosphonic diamide directing group.
Phosphoryl-related directing groups in rhodium(III) catalysis: A general strategy to diverse P-containing frameworks
Zhao, Dongbing,Nimphius, Corinna,Lindale, Matthew,Glorius, Frank
supporting information, p. 4504 - 4507 (2013/09/24)
Herein, a rhodium(III)-catalyzed oxidative C-H activation of simple arylphosphonates and phosphonamides with subsequent coupling with alkenes (olefination), internal alkynes (hydroarylation and oxidative cyclization), or simple arenes to give access to diverse P-containing functional frameworks is reported.
