1451263-44-7Relevant academic research and scientific papers
P-stereogenic PNP pincer-Pd catalyzed intramolecular hydroamination of amino-1,3-dienes
Yang, Zehua,Xia, Chao,Liu, Delong,Liu, Yangang,Sugiya, Masashi,Imamoto, Tsuneo,Zhang, Wanbin
, p. 2694 - 2702 (2015)
A new P-stereogenic PNP pincer-Pd complex was readily prepared from optically pure 2,6-bis[(boranato(tert-butyl)methylphosphino)methyl]pyridine. It was used in the asymmetric intramolecular hydroamination of amino-1,3-dienes, with the desired products bei
Pd(II)-catalyzed intramolecular 1,2-aminoalkylation of conjugated 1,3-dienes for the synthesis of pyrrolizidines
Xing, Dong,Yang, Dan
supporting information, p. 4370 - 4373 (2013/09/24)
A palladium(II)-catalyzed tandem cyclization reaction involving an intramolecular 1,2-aminoalkylation of N-4,6-dienyl β-keto amides has been developed. This process provides an efficient method for the rapid assembly of pyrrolizidines starting from linear substrates in moderate to good yields and high to excellent diastereoselectivities.
