145167-95-9Relevant academic research and scientific papers
Synthesis of enantiopure allylamines by reductive alkylation of amino epoxides with organolithium reagents
Concellon, Jose M.,Suarez, Jose Ramon,Del Solar, Virginia
, p. 349 - 351 (2006)
Transformation of enantiopure (2R,1′S)-2-(1-aminoalkyl)epoxides 1 into the corresponding allylamines 2 is described. The opening of the epoxide ring with different organolithium compounds takes place with total selectivity and in high yields.
Solvent effects on the steric course of the [2,3]-wittig rearrangement of (S,E)-[3-(Allyloxy)prop-1-ene-1,3-diyl]dibenzene and derivatives
Ikemoto, Hidaka,Sasaki, Michiko,Takeda, Kei
supporting information; experimental part, p. 6643 - 6650 (2011/02/25)
The effect of solvents and additives on the steric course of [2,3]-Wittig rearrangement of the chiral 1,3-diphenyl-1-propenyloxy-2-propen-1-yl carbanion and its derivatives wasexamined on the basis of chirality transfer in intramolecular trapping. Copyrig
On the Configurational Stability of α-Hetero-Substituted Benzyllithium Compounds
Hoffmann, Reinhard W.,Ruehl, Thomas,Harbach, Juergen
, p. 725 - 730 (2007/10/02)
A test based on kinetic resolution was applied to probe the configurational stability of various α-substituted benzyllithium compounds 1.It was found that the trimethylsilyl- (1b), phenylsulfenyl (1c), and the phenylselenyl-substituted (1d) benzyllithium
