145236-05-1Relevant academic research and scientific papers
Palladium-catalyzed regio-, diastereo-, and enantioselective allylic alkylation of acylsilanes with monosubstituted allyl substrates
Chen, Jian-Ping,Ding, Chang-Hua,Liu, Wei,Hou, Xue-Long,Dai, Li-Xin
supporting information; experimental part, p. 15493 - 15495 (2011/02/21)
Acylsilanes as a new type of "hard" carbon prenucleophile reacted with monosubstituted allyl reagents under Pd-catalyzed asymmetric allylic alkylation reaction conditions to provide products with high regio-, diastereo-, and enantioselectivities. The usef
Synthesis of acylsilanes via transmetalation of 1-triorganosilyloxyvinyltin derivatives
Verlhac, Jean-Baptiste,Kwon, HeeAn,Pereyre, Michel
, p. C13 - C18 (2007/10/02)
Transmetalation of 1-triorganosilyloxyvinyltin derivatives occurs with a reverse Brook rearrangement.Subsequent trapping with various electrophiles affords new acylsilanes.
