30608-90-3

Basic information

• Product Name: Silane, trimethyl(1-oxopropyl)-
• CAS NO: 30608-90-3
• Molecular Formula: C6H14OSi
• Molecular Weight: 130.262
• Mol File: 30608-90-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(1-oxopropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(1-oxopropyl)-(30608-90-3)
• EPA Substance Registry System: Silane, trimethyl(1-oxopropyl)-(30608-90-3)

Safety Data

• Hazardous Substances Data: 30608-90-3(Hazardous Substances Data)

Upstream product

• 109863-05-0 4,4,5,5-tetramethyl-2-<1-(trimethylsilyl)-1-propenyloxy>-1,3,2-dioxaborolane 
• 100-52-7 benzaldehyde 

Downstream Products

• 1254704-13-6 2-methyl-3-phenyl-1-(trimethylsilyl)pent-4-en-1-one 
• 145236-05-1 C₁₅H₂₂OSi 
• 1254704-24-9 3-(4-chlorophenyl)-2-methyl-1-(trimethylsilyl)pent-4-en-1-one 
• 1254704-25-0 3-(4-bromophenyl)-2-methyl-1-(trimethylsilyl)pent-4-en-1-one 
• 1254704-26-1 3-(4-methoxyphenyl)-2-methyl-1-(trimethylsilyl)pent-4-en-1-one 
• 651738-31-7 [(E)-1-Ethyl-3-(toluene-4-sulfonyl)-propenyl]-trimethyl-silane 
• 104376-28-5 (1-Trimethylsilanyl-3-trimethylsilanyloxy-penta-1,2-dienyl)-benzene 
• 104376-27-4 (Z)-1-Phenyl-1-trimethylsilanyl-pent-1-en-3-one 
• 104376-26-3 (E)-1-Phenyl-1-trimethylsilanyl-pent-1-en-3-one 
• 104376-07-0 (1-Ethyl-3-phenyl-propa-1,2-dienyloxy)-trimethyl-silane 

Relevant articles and documents

Stereoselective Syntheses of Alkohols, XXV. - Generation of Enol Borates and Their Addition to Aldehydes

Ketone-derived enol borates, especially those having a 4,4,5,5-tetramethyl-1,3,2-dioxaborolane unit, are stable compounds,which have been prepared either by borylation of lithium enolates or by oxidation of vinylboronates.These E- or Z-enol borates add to aldehydes in a stereoconvergent reaction leading to syn-aldols.Aldehyde-derived enol borates have a high tendency towards polymerization.Their in-situ addition to aldehydes generates 4-alkoxy-1,3,2-dioxaborinanes, which are internally protected aldols.