145241-79-8

Upstream product

• 110-82-7 cyclohexane 
• 142131-02-0 5-O-benzoyl-3-C-cyano-1,2-O-isopropylidene-3-O-mesyl-α-D-ribofuranose 
• 110-83-8 cyclohexene 

Relevant academic research and scientific papers

1,6-C-H and 1,5-O-Si insertion reactions of alkylidenecarbene derivatives of monosaccharides

A new protocol has been developed for the generation of alkylidenecarbene derivatives of monosaccharides based on the reaction of trimethylsilylazide and Bu2SnO with α-cyanomesylates derived from uloses. When this method is applied to convenien

Alkylidene Carbenes as Intermediates in the Synthesis of Highly Functionalized Branched-chain Sugar and Nucleosides

Reaction of O-mesylcyanohydrins of furanos-3-ulose with sodium azide afforded isomeric vinylazido compounds.A mechanism involving an alkylidene carbene is proposed and the intermediacy of such a carbene is confirmed by standard trapping reactions such as,

Mild Generation of Alkylidenecarbenes from α-Mesyloxynitriles of Sugars. Application to the Synthesis of Branched-chain Sugars

Treatment of O-mesylcyanohydrins of furanos-3-ulose with sodium azide vinylazidoderivatives; the intermediary of an alkylidenecarbene is proposed, and reactions to trap such an intermediate are described.