145241-82-3

Upstream product

• 617-86-7 triethylsilane 
• 142131-02-0 5-O-benzoyl-3-C-cyano-1,2-O-isopropylidene-3-O-mesyl-α-D-ribofuranose 

Relevant academic research and scientific papers

Alkylidene Carbenes as Intermediates in the Synthesis of Highly Functionalized Branched-chain Sugar and Nucleosides

Reaction of O-mesylcyanohydrins of furanos-3-ulose with sodium azide afforded isomeric vinylazido compounds.A mechanism involving an alkylidene carbene is proposed and the intermediacy of such a carbene is confirmed by standard trapping reactions such as,

Mild Generation of Alkylidenecarbenes from α-Mesyloxynitriles of Sugars. Application to the Synthesis of Branched-chain Sugars

Treatment of O-mesylcyanohydrins of furanos-3-ulose with sodium azide vinylazidoderivatives; the intermediary of an alkylidenecarbene is proposed, and reactions to trap such an intermediate are described.