Alkylidene Carbenes as Intermediates in the Synthesis of Highly Functionalized Branched-chain Sugar and Nucleosides

DOI: 10.1016/S0040-4020(01)85250-9

Source and publish data:

Tetrahedron p. 7269 - 7282 (1994)

Update date:2022-07-29

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Authors:

Perez-Perez, Maria-Jesus

Camarasa, Maria-Jose

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Article abstract of DOI:10.1016/S0040-4020(01)85250-9

Reaction of O-mesylcyanohydrins of furanos-3-ulose with sodium azide afforded isomeric vinylazido compounds.A mechanism involving an alkylidene carbene is proposed and the intermediacy of such a carbene is confirmed by standard trapping reactions such as,

Full text of DOI:10.1016/S0040-4020(01)85250-9

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