1452876-13-9Relevant academic research and scientific papers
Directed: Ortho C-H borylation catalyzed using Cp?Rh(iii)-NHC complexes
Thongpaen, Jompol,Schmid, Thibault E.,Toupet, Loic,Dorcet, Vincent,Mauduit, Marc,Baslé, Olivier
supporting information, p. 8202 - 8205 (2018/07/29)
Cp?Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild conditions.
PdCl2 and N-hydroxyphthalimide co-catalyzed c sp 2 -H hydroxylation by dioxygen activation
Yan, Yuepeng,Feng, Peng,Zheng, Qing-Zhong,Liang, Yu-Feng,Lu, Jing-Fen,Cui, Yuxin,Jiao, Ning
supporting information, p. 5827 - 5831 (2013/06/27)
Rad transition: The combination of transition-metal-catalyzed C-H activation and a NHPI-initiated radical process is essential for the title transformation. The neutral conditions and the ideal oxidant, molecular oxygen, make this hydroxylation environmen
